ColumnHeader ch_FileName = new ColumnHeader();
ch_FileName.Text = "File Name";
ch_FileName.Width = 110;

ColumnHeader ch_FileLocation = new ColumnHeader();
ch_FileLocation.Text = "File Path";
ch_FileLocation.Width = 110;

listView1.Columns.AddRange(new System.Windows.Forms.ColumnHeader[]{
ch_FileName, ch_FileName});

OpenFileDialog openFile = new OpenFileDialog();
if(openFile.ShowDialog() == DialogResult.OK)
{
  foreach(string file in openFile.FileNames)
  {
     string fileName = System.IO.Path.GetFileNameWithoutExtension(file);
     ListViewItem item = new ListViewItem(new string[]{
         fileName, file});
     listView1.Items.Add(item);
  }
}

------解决方案--------------------
楼上写的很清楚了，不过要再设置一下打开对话框多选。

openFile.Multiselect=true; //这样才可以多选文件